When is something dissolved and undissolved in a solvent?
For example, I know that ionic compounds dissolve in polar water through hydration KA(s) <–> K+(aq) + A-(aq). Then I came across the definition of the dissociation constant ([K+][A-])/[KA]. But now I'm wondering what [KA] actually means, since concentration is defined as mol/l of dissolved substance, but KA is not dissolved, unlike K+ and A-. If I pour salt into 1L of water and at some point the solubility product is exceeded, salt precipitates. Does this precipitated salt still count as [NaCl]? If not, how do I distinguish whether a solid sediment is part of it (in visible quantities) or whether the invisible NaCl is already part of the equilibrium reaction?
In the calculation of the dissociation, the “concentration” of the undissolved solid is defined as =1 and thus it is shortened from the calculation. Only the concentrations of the dissolved ions remain. So if you want to know if a certain amount of substance dissolves in your solvent, you should calculate the solubility product (the definition of dissociation specified above) and then calculate again whether your desired amount in solution would exceed this concentration or not.