Similar Posts

Subscribe
Notify of
11 Answers
Oldest
Newest Most Voted
Inline Feedbacks
View all comments
indiachinacook
1 year ago

Chloroacetic acid has pKa=2.86, which is clearly not a strong acid (which would have to be completely dissociated, pKa <0), but also not really weak anymore, because it is noticeably dissociated in aqueous solution:

In this chart you can see a lot. The dilution is carried out on the x-axis (x=2 corresponds to c=10 ̄2 mol/l=0.01 mol/l), the black curve is the pH for chloroacetic acid, the white curve is the derivative thereof and the orange is the pH value which is obtained with the formula for weak acids, and the background colors indicate which proportions of free chloroacetic acid (red) and chloroacetate (red) are present.

You clearly see that chloroacetic acid is already distinctly dissociated in relatively concentrated solution (blue content), and at c <0.001 mol/l it is practically a strong acid, i.e. completely dissociated; the formula for weak acids therefore only functions at c>0.01 mol/l. It is therefore fair to say that chloroacetic acid falls within the limit between strong and weak; for example, it is not possible to use as a buffer substance in a conventional manner, or more precisely only at c>0.001 mol/l.

For comparison there is the same graph for acetic acid. You see that acetic acid is also largely strong at very high dilution, i.e. completely dissociated, but this only happens at c≪0.0001 mol/l. That is why it is justified to call acetic acid “weak” — who has ever been dealing with acetic acid solutions in concentration 10 ̄5 mol/l?

indiachinacook
1 year ago
Reply to  Gifsi

Acids with pKa77 are slightly dissociated at any concentration, so everyone will call them weak. Conversely, pKa means complete dissociation at any concentration, so the strong acids are.

Well, there are different answers, depending on who you ask. However, most people would agree that acetic acid (pKa=4.75) is weak, and that phosphinic acid (pKa1=2.15) is medium.

anwesende
1 year ago

there is no uniformly defined pKs value for a strong, moderately strong or weak acid.

If you find googels you find many -very different- details. https://www.google.com/search?q=strong+s%C3%A4uren+pks

Only in the view that a strong acid is virtually completely dissociated even at higher concentrations is one united.

m.f.G.

present

NaturCBP
1 year ago

Up to 2.0 are called strong acids. If the value is 4.5, it is moderate. Because the very strong have a negative value.

ADFischer
1 year ago

Chloroacetic acid is a strong acid (more powerful than acetic acid).

ADFischer
1 year ago
Reply to  Gifsi

The pKs is 2.9.

ADFischer
1 year ago

Weak acids start at about 8.