H-atom attracted to radical?

In the radical substitution reaction, the H atom is attracted to the halogen radical in the first chain propagation step.

Why is that ? And what about the halogen bromine?

(Hydrogen atom of the alkane on the right side is attracted to the halogen Cl)

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PWolff
1 year ago

In the case of chlorine, it should be quite clear – the electronegativity of chlorine is significantly higher than that of carbon, so it is to be expected that chlorine can also bind protons (hydrogen ions).

In the case of bromine, it is more complicated – in this case, even energy must be used in order to transfer an H to the Br radical. After all, in the microcosm, everything that can happen in any way happens only the less often, the more energy (or comparable) it costs, and then it will be reversed more quickly.

(See the results of a web search by

radical substitution brom

probably the hit

https://www.studysmarter.de/schule/chemie/organic-chemie/radikalische-substitution/

suitable to understand a little more.)

If a sufficiently stable end product is produced, one has luck – then there is enough left of the end product.